Carboxylic acidsReactions of carboxylic acids

A common carboxylic acid is ethanoic acid, vinegar. Carboxylic acids are weak acids that react in the same way as other acids. They are responsible for the rancid flavour and smell of off food.

Part of ChemistryNature's chemistry

Reactions of carboxylic acids

Carboxylic acids can undergo reduction reactions. Reduction is the opposite of oxidation.

For example, ethanoic acid (CH3COOH) can be formed by the oxidation of ethanol as shown below.

Ethanoic acid formation

As reduction is the opposite of oxidation, it can be defined as the removal of oxygen or the addition of hydrogen to a molecule.

Ethanoic acid reduction

Carboxylic acids can also react with bases to form a salt and water in neutralisation reactions. When long chain 'fatty' acids are used, the salt formed is a soap.

For example:

\(C_{17}H_{33}COOH + NaOH \rightarrow C_{17}H_{33}COONa + H_{2}O\)

sodium oxide + butanoic acid → sodium butanoate + water

potassium hydroxide + oleic acid → potassium oleate + water

copper carbonate + ethanoic acid → copper ethanoate + water + carbon dioxide