Controlling the rate of reactionsMeasuring rates of reaction

Rate of reaction is a measure of how fast a reaction takes place. In industry, chemists control rates of reaction to ensure the production is safe but still fast enough to keep up with demand.

Part of Chemistry (Single Science)Making useful chemicals

Measuring rates of reaction

There are different ways to determine the rate of a reaction. The method chosen usually depends on the and involved, and how easy it is to measure changes in them.

In addition, how long a reaction is observed for depends on the rate of reaction. Reactions can vary from being almost instantaneous to taking years to complete. In the lab, reactions are usually followed over a few seconds or minutes.

Question

is a slow reaction. Give four examples of a very fast reaction.

Measuring mass

The change in of a reactant or product can be followed during a reaction. This method is useful when carbon dioxide is a product which leaves the reaction container. It is not suitable for hydrogen and other gases with a small , Mr. The units for rate are usually g/s or g/min.

Measuring volume

The change in of a reactant or product can be followed during a reaction. This method is useful when a gas leaves the reaction container. The volume of a gas is measured using a gas syringe, or an upside down . An upturned measuring cylinder can also be used but this is less . The units for rate are usually cm3/s or cm3/min.

Methods to measure volume of gas collected.
Figure caption,
Two ways to measure the volume of a gas produced in a reaction

Measuring colour change or formation of a precipitate - Higher

A few reactions produce a colour change, for example due to the production of iodine. A colorimeter measures colour change.

The formation of a causes the reacting mixture to change from transparent to . The rate of reaction can be measured by timing how long it takes for a cross (drawn on a white tile) to disappear.

The result of adding dilute acid to a transparent sodium thiosulfate solution is a more opaque solution.

Graphs

The rate of reaction can be analysed by plotting a graph of mass or volume of product formed against time. The graph shows this for two reactions.

Graph of total mass of product against time from start of reaction. A line labelled 'fast reaction' rises sharply from zero before gradually levelling off. A line labelled 'slow' reaction rises less sharply but eventually levels off at the same height as the fast reaction line.
  • the horizontal line shows that no more product is being made - the reaction has finished
  • rate of reaction does not affect the mass of product formed

The or steepness of the line is equal to the rate of reaction:

  • the steeper the line, the greater the rate of reaction
  • fast reactions finish sooner (when the line becomes horizontal) than slow reactions