Controlling the rate of reactionsCatalysts

Rate of reaction is a measure of how fast a reaction takes place. In industry, chemists control rates of reaction to ensure the production is safe but still fast enough to keep up with demand.

Part of Chemistry (Single Science)Making useful chemicals

Catalysts

A is a substance that increases the rate of reaction, but can be recovered, unchanged at the end.

Only a very small of catalyst is needed to increase the rate of a reaction. However, not all reactions have suitable catalysts.

Different substances catalyse different reactions. The table describes three common catalysts.

CatalystReaction catalysed
IronThe Haber process (making ammonia)
Vanadium (V) oxideThe contact process (a stage in making sulfuric acid)
Manganese dioxideDecomposition of hydrogen peroxide (produces water and oxygen)
CatalystIron
Reaction catalysedThe Haber process (making ammonia)
CatalystVanadium (V) oxide
Reaction catalysedThe contact process (a stage in making sulfuric acid)
CatalystManganese dioxide
Reaction catalysedDecomposition of hydrogen peroxide (produces water and oxygen)

Notice that these catalysts are transition metals or of .

How catalysts work

A catalyst provides an alternative that has a lower than the uncatalysed reaction. This does not change the rate of collisions. However, it does increase the rate of successful collisions because a greater proportion of collisions now exceeds this lower activation energy.

The effect of a catalyst on the activation energy is shown on a chart called a . This shows how the energy of the and change during a reaction.

A reaction profile for a reaction with and without a catalyst
Figure caption,
A reaction profile for a reaction with and without a catalyst

Enzymes

An is a biological catalyst. Enzymes are important for controlling reactions in the cells of living organisms. They work best within a narrow range of temperature and .

Some enzymes can be adapted or made for use in industry. The conditions that the enzymes work in is limited but this can bring benefits. For example, the use of enzymes allows some industrial reactions to happen at lower temperatures and pressures than traditionally needed. This helps to reduce energy demands.

Enzymes are used in everyday products such as washing powders, where they break down food stains.

is a single-celled . The enzymes in yeast are used to produce wine, beer and other alcoholic drinks by of sugars.