Nanoparticles - (CCEA)

Part of Chemistry (Single Science)Unit 1: Structures, trends, chemical reactions, quantitative chemistry and analysis

What are the key learning points about nanoparticles?

  • Nanoparticles are particles which are between 1 and 100 nanometres in size and contain a few hundred atoms.

  • They have different properties compared to larger particles, this is due to their high surface area to volume ratio.

  • Nanoparticles have a wide range of potential uses, though there are some concerns their use could have unwanted effects.

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What are nanoparticles?

Nanoparticles are particles which are between 1 and 100 nanometres (nm) in size and are made up of a few hundred .

One nanometre is 1 × 10-9m or 0.000000001 m.

The properties of nanoparticles are different from those of the same atoms in bulk such as powders, lumps or sheets.

For example, a nanoparticle of gold will behave differently to a lump of gold, even though they both contain the same type of atom.

Buckminsterfullerene, C<sub>60</sub>, is a nanoparticle
Figure caption,
Buckminsterfullerene, C60, is a nanoparticle
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What is surface area to volume ratio?

The reason that nanoparticles have different properties to bulk materials is that they have a high to .

A surface area to volume ratio is a measurement of how the surface area of a shape compares to the volume of the same shape.

Smaller structures have a larger surface area to volume ratio than larger ones.

You can demonstrate this mathematically.

Surface area to volume ratio

When the length of a side of a cube is decreased by a factor of 10 (10 cm to 1cm), the increases by a factor of 10 (0.6:1 to 6:1).

Question

Calculate the surface area to volume ratios for a cube with side length 20cm, and a cube with side length 2 cm.

A cube with side length 20cm, and a cube with side length 2 cm.

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Why are nanoparticles used in sun cream?

The interesting properties of nanoparticles mean they have a wide range of potential uses.

Nanoparticles are already common in sun creams.

There are some benefits and concerns of using nanoparticles in sun creams.

BenefitsConcerns
Better skin coverageNanoparticles may enter cells and cause cell damage
Better protection from the sun’s raysCould wash off skin and cause harm to the environment
Colourless once rubbed onto skinRisks are difficult to determine as nanoparticles have not been in use for very long
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How much do you know about nanoparticles?

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